Resources - Safety Info
Banned and Restricted Chemicals:
Some Problematic Issues and a Suggested Future Direction
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From November 1996 issue of ‘Crucible’
Volume 28.2
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Over the last decade, a pressing issue that has been hotly
debated and discussed among science teachers in Ontario, and for that
matter, throughout North America, has been the often contentious reactions
to Board implemented bans and restrictions on the use of certain chemicals.
The purpose of this article is to explore some of the issues that surround
these bans and restrictions.
As science teachers, and members of the STAO Safety Committee,
we are acutely aware of the implications of such bans and restrictions.
They obviously have an impact on what sorts of teacher demonstrations
and student lab activities can be done. As well, in this era of increased
litigations, they introduce potentially career-threatening implications
for science teachers should non-compliance result in a negligence claim.
At the outset, it is important that we state the position of the STAO
Safety Committee.
- Belief 1 - Student experimentation is central to modern
science education.
- Belief 2 - Proper attitude, knowledge, and common sense
regarding safety must be practiced by both teachers and students.
- Belief 3 - The teacher must ensure that students understand
the potential dangers inherent lab settings, and in the specific lab
activities they engage in.
- Belief 4 - Hazardous experiments should not necessarily
be removed from the curriculum, but they should be made safer so that
the risk is reduced.
- Belief 5 - The opportunity to instruct students on
the proper use of hazardous materials usually outweighs by far the false
sense of security we gain by banning them.
- Belief 6 - Informed science teachers should decide
which chemicals have associated risks that are so great they outweigh
the educational value of the chemical's use.
With these principles in mind, we set out to discover
which chemicals are banned or restricted in a variety of jurisdictions.
From this compilation, we have identified several problematic issues and
have suggested a future direction.
The Data
Lists of banned and restricted chemicals were obtained
from nine Ontario school Boards, from both urban and rural areas. We also
obtained similar lists from British Columbia and the United Kingdom. Some
examples of banned and restricted chemicals are shown below.
Banned
| |
Ont. (n=9) |
B.C. |
U.K. |
| Barium & compounds |
|
|
|
| Benzene |
6 |
x |
x |
| Benzo(a)pyrene |
2 |
|
|
| Benzoyl peroxide |
7 |
x |
x |
| Beryllium & compounds |
3 |
x |
x |
| Bromine (liquid) |
3 |
x |
|
| Bromine water |
|
|
|
| Cadmium & compounds |
6 |
x |
|
| Calcium |
|
|
|
| Calcium hydride |
2 |
x |
|
| Calcium oxide (quicklime) |
|
|
|
| Carbon disulfide |
6 |
x |
x |
| Carbon tetrachloride |
6 |
x |
x |
Restricted
| |
Ont. (n=9) |
B.C. |
U.K. |
| Barium & compounds 2 x x |
2 |
x |
x |
| Benzene |
|
|
|
| Benzo(a)pyrene |
|
|
|
| Benzoyl peroxide |
|
|
|
| Beryllium & compounds |
|
|
|
| Bromine (liquid) |
4 |
|
x |
| Bromine water |
3 |
|
x |
| Cadmium & compounds |
|
|
x |
| Calcium |
2 |
|
x |
| Calcium hydride |
2 |
|
x |
| Calcium oxide (quicklime) |
2 |
|
x |
| Carbon disulfide |
2 |
|
|
| Carbon tetrachloride |
1 |
|
|
Even this short sampling (from our list of 115 chemicals)
illustrates many of our concerns regarding bans and restrictions. Some
Ontario Boards had quite extensive and comprehensive lists, whereas others
had very short lists. As well, there was remarkable similarly between
several of the Ontario Board lists which, at face value, suggests a strong
degree of agreement between the two jurisdictions. On closer examination,
it becomes obvious that one of the Boards relied heavily on the document
of the other, even citing it as a major reference.
Concern 1: Macro versus Micro
In Ontario, each school Board has produced its own list
of banned and restricted chemicals (although there is currently an increase
in collaboration among several urban Boards), while both British Columbia
and the U.K. have one official document that applies to the entire geographic
area. In fact, the British Columbia and U.K. lists are quite comprehensive
in their breadth and depth and provide information about the dangers of
each chemical regardless of whether it carries the designation of being
banned or restricted. Few of the Ontario lists can make the same claims,
but for good reason. It takes a tremendous amount of energy and dedication
by a group of people (typically science teachers) to generate such chemical
lists. Thus, it should not be surprising that the breadth and depth of
Ontario lists vary widely, nor should it be surprising when one Board's
list is almost entirely adopted by another Board.
Concern 2: Banned versus Restricted
Ideally, Boards would ban chemicals that violate safety
belief #6 and restrict chemicals that are consistent with the spirit of
safety beliefs #4 and #5. Several of the chemical lists from Ontario Boards
comprised only banned chemicals, and did not even use the "restricted
chemical" designation. Our survey indicates that there is broad agreement
about the designation of some chemicals (e.g. benzene and benzoyl peroxide),
general trends about the designation of some others (e.g. carbon disulfide
and carbon tetrachloride), but little agreement about the designation
of some others (e.g. liquid bromine and calcium hydride). What is really
needed is a clear criterion for designating chemicals as banned or restricted,
and this requires leadership and direction from the Ministry of Education
and Training, rather than having this exercise done on a Board by Board
basis.
Concern 3: Breadth of Lists
It is worrying that there is lack of agreement by different
Boards on the proper designation of certain chemicals. In the case of
benzene, for example, six Boards banned its use. Why did this substance
not appear on the lists of the other three Boards? Was it because they
deemed its use to be acceptable, or was it because this chemical had been
overlooked? There is a real issue to be addressed, in that different Ontario
Boards have apparent lack of consistency regarding the appropriateness
of certain chemicals for use in the classroom
Concern 4: Depth of Lists
From some Boards, the list of banned chemicals comprised
20 or so chemicals, without any rationale for their inclusion. In other
cases, very detailed documents have been produced that identify the hazards
associated with each chemical (not just those that are designed as banned
or restricted). Some Boards chose to include National Fire Protection
Association (NFPA) chemical safety information (which uses the four-coloured
diamond as a means of conveying health, flammability, reactivity, and
special case dangers on a 0-4 scale). Of course, it should not be surprising
to know that in some cases, there is even disagreement about the NFPA
values for a given chemical (which is probably due to differences among
chemical suppliers). None of the lists from any jurisdiction made any
suggestions regarding safer alternative chemicals that could be used.
If the educational value of certain student lab activities and teacher
demonstrations is not in question, then we need to look for alternatives
that do not have the associated risks present in the banned chemical.
Conclusion and Recommendations
We recognize that raising these concerns regarding banned
and restricted chemicals may rekindle some of the vociferous debates surrounding
the issues. It is important to bring these concerns to light because we
live in an age where someone can successfully sue a company because they
spill the company's hot coffee in their own lap. More important, the concerns
that have been raised clearly point to the importance of leadership and
direction that can only come from the Ministry of Education and Training.
Each school Board should not have to repeat the process of developing
a comprehensive list of chemicals, identifying their dangers, designating
some of the chemicals as banned or restricted, and making suggestions
regarding safer alternatives. This Board by Board approach currently applies
to the creation of laboratory emergency and safety procedures as well.
The Ministry of Education and Training needs to make a commitment to providing
much more leadership in this area of health and safety. The development
of a comprehensive Safety Manual, that states a uniform policy for all
school Boards and science teachers of Ontario, would seem to be long overdue.
References
The Association for Science Education (1988) Topics in
Safety. London: ASE. pp. 50-62.
British Columbia Ministry of Education (1990) Science
Safety Resource Manual. Victoria: Province of British Columbia.
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